Experimental measurements and modelling of vapour−liquid equilibria for four mixtures of 2,3,3,3−tetrafluoropropene (R1234yf) with 1,1,1,2−tetrafluoroethane (R134a) or 1,1−difluoroethane (R152a) or trans−1−chloro−3,3,3−trifluoropropene (R1233zd(E)) or 2−chloro−3,3,3−trifluoropropene (R1233xf)

Isothermal vapour−liquid equilibrium (VLE) for four binary systems involving R1234yf (R1234yf + R134a, R152a, R1233zd(E) and R1233xf) were measured at temperatures from 278.15 to 348.15 K. The experiments conducted by means of a “static−analytic” apparatus with phase analysis via gas chromatography, resulting uncertainties 0.6 K temperature, 8 kPa pressure maximum 0.007 vapour liquid mole fractions. main advantage the equipment is that samples are taken phases two capillary samplers (ROLSI®). Peng Robinson Equation State considered represent experimental data. If possible, comparison between new data prediction REFPROP 10.0 software realized.